New Production of Sapphire from Matepwende, Tanzania

Figure 1. Blue sapphires from the Matepwende area in southern Tanzania. Most of the production consists of low-clarity material in matrix. Only a very small percentage (usually weighing less than 1 ct) is clean enough to be faceted. Photo by Vincent Pardieu.

Figure 1. Blue sapphires from the Matepwende area in southern Tanzania. Most of the production consists of low-clarity material in matrix. Only a very small percentage (usually weighing less than 1 ct) is clean enough to be faceted. Photo by Vincent Pardieu.

In February 2024, Mark Saul (Amor Gems, Kenya) informed author VP about a sapphire rush near Matepwende village, located in the Namtumbo district in Songea, in southern Tanzania. News of a rush involving several thousand migrant miners from all around the country was soon publicized on Tanzanian television.

The following month in Bangkok, VP acquired a parcel of “F-type” reference samples (according to the GIA classification system) (W. Vertriest et al., “Field gemology: Building a research collection and understanding the development of gem deposits,” Winter 2019 G&G, pp. 490–511; V. Pardieu, “Field gemology, the evolution of data collection,” InColor, No. 46, 2020, pp. 100–106) reportedly from the new deposit for preliminary study (figure 1). Some were used for a heat treatment experiment in Thailand, and 27 others were sent to author AP for gemological study.

While samples were being studied at GIA, VP visited the new deposit in early June 2024 with geologists Leonard Cornuz and Yedidia Mgema. The site is in a remote area about five hours’ drive from Songea using dirt roads during the dry season. It is 7 km north of the Ruvuma River bordering Mozambique. Geologically, it lies at the boundary between the Luwegu sedimentary sub-basin (part of the Selous basin) and the metamorphic Usagaran Belt. A uranium prospective license covers most of the deposit.Figure 2. A: Large grayish blue sapphire crystals (about 5 cm) in white feldspar. B: Geologists check a sapphire-rich pegmatite in an artisanal mining excavation near Matepwende. C: A small deep blue facet-grade sapphire fragment within a heavily fractured sapphire crystal associated with (whitish) feldspar and (dark) mica. Photos by Vincent Pardieu.

Figure 2. A: Large grayish blue sapphire crystals (about 5 cm) in white feldspar. B: Geologists check a sapphire-rich pegmatite in an artisanal mining excavation near Matepwende. C: A small deep blue facet-grade sapphire fragment within a heavily fractured sapphire crystal associated with (whitish) feldspar and (dark) mica. Photos by Vincent Pardieu.

The deposit is a primary hard rock deposit where blue sapphires are associated with feldspar and mica in pegmatites intruding into gneisses (figure 2). Most of the sapphires are inside the pegmatites, while others are found in a mica-rich reaction zone between the pegmatite and the gneiss, indicating a desilicated pegmatite deposit (G. Giuliani et al., “The geology and genesis of gem corundum deposits,” in L.A. Groat, Ed., The Geology of Gem Deposits, 2007, Mineralogical Association of Canada Short Course Series). Most of the mining activity occurred in the nearby detrital deposit over and near the pegmatites and in the limited secondary deposits along streams. The site of the rush covered approximately 1 square kilometer. About 400 artisanal miners (mostly from the Songea or Tunduru) were in the area during VP’s visit, down from 1,000 a few weeks earlier at the height of the rush. About half were directly involved in mining, while the others were buying gems or providing supplies to the miners.Figure 3. Left: Two miners with kilos of sapphire rough. Right: The result of their work after breaking the heavily fractured sapphires into attractive parcels of small sapphire. Photos by Vincent Pardieu.

Figure 3. Left: Two miners with kilos of sapphire rough. Right: The result of their work after breaking the heavily fractured sapphires into attractive parcels of small sapphire. Photos by Vincent Pardieu.

The best facet-grade, fine-color sapphire seen during the expedition was a deep blue stone weighing about 2 ct, while the other fine stones were under 1 ct. We also saw kilos of heavily fractured and twinned corundum specimens up to 500 g, locally called “cabochons,” that are broken to extract fragments of blue facetable material to be used for calibrated stones (figure 3). Most of these stones were industrial-, carving-, or bead-grade. According to locals, the deposit has been a known source of this material for more than 30 years. While some of the stones have an attractive blue coloration, most have a grayish overtone. Regarding clarity, most stones exhibit polysynthetic twinning and fractures, and more than half are also milky/silky. A heat treatment experiment under reducing conditions was conducted in Thailand by Karim Guerchouche from Premacut Ltd. The stones did not improve with heat treatment.Figure 4. Representative UV-Vis-NIR spectra of Matepwende sapphire. Half of the samples showed a standard magmatic-type UV-Vis-NIR spectrum with a prominent 880 nm band and Fe

3+-related features, while the other half showed a nonclassical spectrum without a prominent 880 nm band but with prominent Fe

3+-related features.

Author AP used 12 sapphires from the deposit for a preliminary study, splitting the material into two groups based on their ultraviolet/visible/near-infrared (UV-Vis-NIR) spectra (figure 4). One group of six samples had UV-Vis-NIR spectra more typically seen in basalt-related sapphires, such as those from Australia or Thailand, with a prominent broad band absorption at 880 nm and significant Fe3+-related features at 377, 388, and 450 nm. These are often called “magmatic-type” or “CMG” sapphires. The other group of six samples lacked the prominent 880 nm band but still had significant Fe3+-related features. These are often called “nonclassical” (NCL) sapphires, and they include sapphires from Montana in the United States and both Umba and Songea in Tanzania.Figure 5. Platelet-type inclusions (left) and reflective silk (right) in the Matepwende sapphires with a magmatic-type UV-Vis-NIR spectrum. Photomicrographs by Aaron Palke; fields of view 1.58 mm (left) and 1.26 mm (right).

Figure 5. Platelet-type inclusions (left) and reflective silk (right) in the Matepwende sapphires with a magmatic-type UV-Vis-NIR spectrum. Photomicrographs by Aaron Palke; fields of view 1.58 mm (left) and 1.26 mm (right).Figure 6. Bronzy reflective silk in dense linear bands (left) and as stringers (right) in the Matepwende sapphires with a nonclassical-type UV-Vis-NIR spectrum. Photomicrographs by Aaron Palke; fields of view 1.99 mm (left) and 2.90 mm (right).

Figure 6. Bronzy reflective silk in dense linear bands (left) and as stringers (right) in the Matepwende sapphires with a nonclassical-type UV-Vis-NIR spectrum. Photomicrographs by Aaron Palke; fields of view 1.99 mm (left) and 2.90 mm (right).

The inclusion characteristics were different between these groups. The CMG-type sapphire from Matepwende generally displayed platelet-type inclusions and reflective silk that appeared white under strong fiber-optic light (figure 5). Twinning was also common in this group. The NCL-type sapphire from Matepwende, on the other hand, had reflective silk, sometimes in linear bands or stringer-type inclusions that appeared brassy or yellow with reflected fiber-optic light (figure 6). In these NCL-type Matepwende sapphires, the silk also took on a grayish cast with transmitted brightfield light.Table 1. Trace element concentrations (in ppma) of Matepwende sapphires, measured by LA-ICP-MS.

Despite these differences, the trace element chemistry of both groups was very similar and matched more closely with that expected of basalt-related blue sapphire, with relatively low magnesium and elevated iron and gallium (table 1). Fourier-transform infrared (FTIR) spectra for both groups were also very similar. All the sapphires had a prominent 3309 cm–1 peak and a pair of peaks at 3394 and 3379 cm–1. A few samples showed the presence of boehmite in FTIR as well. The difference in UV-Vis-NIR spectra between these two groups was unexpected, given that they were reportedly from the same deposit. The authors had never witnessed such a case, where a single geographical locality produced sapphires displaying two distinct types of UV-Vis-NIR spectra. However, the similarity in trace element chemistry and FTIR spectra suggests a genetic link between these two groups of sapphire from Matepwende. Based on observations during the visit to the deposit, one possible explanation is that the CMG sapphires could have formed inside the pegmatite, while the NCL samples could have formed inside the reaction zone. A study of the material collected at the mine from the pegmatites and reaction zones could help to confirm this hypothesis.

0 replies

Leave a Reply

Want to join the discussion?
Feel free to contribute!

Leave a Reply